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US Secretary of State John Kerry outlined a framework document under which Syria must hand over a full list of its stockpile within a week.
The US-Russia deal on Syria's chemical weapons is a "victory" that averts war, a Syrian minister says.
The framework document says Syria must provide full details of its stockpile within a week - with the chemical arsenal eliminated by mid-2014.
If Syria fails to comply, the deal could be enforced by a UN resolution with the use of force as a last resort.
The US had threatened to attack Syria which it blames for a chemical attack in August which killed hundreds.
President Bashar al-Assad's government denies the allegations and has accused the rebels of carrying out the attack.
Syria recently agreed to join the global Chemical Weapons Convention, and the UN said it would come under the treaty from 14 October.
The framework deal was announced on Saturday after three days of talks in Geneva by Russian Foreign Minister Sergei Lavrov and US Secretary of State John Kerry.
"Start Quote
End QuoteAfter two-and-a-half years during which Russia and the United States have mostly been at loggerheads over what to do about Syria, the two sides have finally collaborated on an issue fraught with political and technical dangers"
"We welcome the agreement," Syrian Reconciliation Minister Ali Haidar told Russian news agency Ria Novosti, giving his country's first reaction.
"On the one hand, it helps Syria come out of the crisis and, on the other, it helps avoid the war against Syria depriving those who wanted to launch it of arguments to do so," Mr Haidar said.
"It's a victory for Syria achieved thanks to our Russian friends."
On Saturday, US President Barack Obama said in a statement that the deal was an "important step" but urged Syria to "live up to its public commitments".
"If diplomacy fails, the United States remains prepared to act," he said.
The Pentagon said the US military was still in position for military strikes.
China, France, the UK, the UN and Nato have all expressed satisfaction at the agreement.
'Last-ditch' optionMr Kerry outlined a timetable that analysts said was extremely ambitious.
It envisages Syria providing a full inventory of its chemical weapons in one week, all production equipment being destroyed by November, and all weapons being removed from Syria or destroyed by mid-2014.
Mr Kerry and Mr Lavrov said a UN resolution could be sought under Chapter VII of the UN charter, which allows for the use of force, if Syria fails to comply.
Agreed target dates
- Completion of initial on-site inspections by November
- Destruction of production and mixing equipment by November
- Complete elimination of all chemical weapons material and equipment in the first half of 2014
However the Russian foreign minister said force remained a last-ditch option.
Russia and the US have agreed on an assessment that the Syrian government possesses 1,000 tonnes of chemical agents and precursors, according to a US official.
The US believes the materials are located in 45 sites, all in government hands, half of which have useable quantities of chemical agents.
But it is thought that Russia does not agree on the number of sites, nor that they are all under the government's control.
The military leader of the anti-Assad Free Syrian Army has rejected the deal, saying it it a ploy by Russia to buy time for President Assad.
Mr Kerry landed in Israel on Sunday for talks with Prime Minister Benjamin Netanyahu.
Before the talks, Mr Netanyahu said it was too early to assess the Syria deal.
"These understandings will be judged on their results - the complete destruction of all of the chemical weapons stockpiles that the Syrian regime has used against its own people," he said.
Mr Kerry is due to go to Paris to meet his French, British and Saudi counterparts on Monday.
More than 100,000 people have died since the uprising against President Assad began in 2011.
Millions of Syrians have fled the country, mostly to neighbouring nations. However, on Saturday, Italy's coastguard said more than 500 people, mostly Syrians, had been rescued off the Italian coast.
Millions more have been internally displaced within Syria.
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